Pointer instruments are useless for very accurate measurements: the best of them have an intrinsic error of about 1 percent of full scale. Where greater accuracy than this is required, elaborate measuring circuits are used. One of the most versatile of these, due to Poggendorf, is the potentiometer. It consists of a uniform wire, AB as represented in the diagram below, about a meter long; through it an accumulator X maintains a steady current I. since the wire is uniform, its resistance per centimeter, R, is constant; the voltage drop across 1 cm of the wire, R1 is therefore also constant.

The potential difference between the end A of the wire, and any point C upon it, is thus proportional to the length of wire *l* between A and C;

*V*_{AC }α *l*. . . . .

**Comparison of E.M.F.s**

To illustrate the use of the potentiometer, let us suppose that we take a cell, Y in the diagram below and join its positive terminal to the point A (to which the positive terminal of X is also joined). We connect the negative terminal of Y, via a sensitive galvanometer, to a slider S, which we can press on to any point in the wire. Let us suppose that the cell Y has an e.m.f. E, which is less than the potential difference V_{AB} across the whole of the wire. Then if we press the slider on B, a current I’ will flow through Y in opposition to its e.m.f. This current will deflect the galvanometer G let us say to the right. If we now press the slider on A, the cell Y will be connected straight across the galvanometer, and will deliver a current I” in the direction of its e.m.f. The galvanometer will therefore show a deflection to the left. If the deflections at A and B are not opposite, then either the e.m.f. of Y is greater than the potential difference across the whole wire, or we have connected the circuit wrongly. The commonest mistake in connecting up is not joining both positives to A.

Now let us suppose that we place the slider on to wire at a point a few centimeters from A, then at a point a few centimeters farther on, and so forth. (We do not run the slider continuously along the wire, because the scarping would destroy the uniformity.) When the slider is at a point C near A the potential difference *V*_{AC} is less than the e.m.f. E of Y; current therefore flows through G in the direction of E, and G may deflect to the left. When the slider is at D near B, *V*_{AB} is greater than E, current flows through G in opposition to E, and G deflects to the right. By trial and error (but no scarping of the slider) we can find a point F such that, when the slider is pressed upon it, the galvanometer shows no deflection. The potential difference *V*_{Af} is then equal to the e.m.f. E; no current flows through the galvanometer because E and V_{AF} act in opposite directions in the galvanometer circuit. Because no current flows, the resistance of the galvanometer, and the internal resistance of the cell, cause no voltage drop; the full e.m.f. E therefore appears, between the points, A and S, and is balanced by *V*_{AF}:

E = *V*_{AF}.

If we now take another cell of e.m.f E_{}, and balance it in the same way, at a point H, then

E_{} = *V*_{AH}

The potential differences *V*_{AF, }*V*_{AH} are proportional to the lengths *l, l*_{} from A to F, and from A to H, respectively.

**Accuracy**

- When the potentiometer is used to compare the e.m.f.s of cells, no errors are introduced by the internal resistances, because no current flows at the balance points.

- The potentiometer is more accurate than an electrometer instrument, which like a moving-coil voltmeter, has an intrinsic error of about 1 percent of full scale. The accuracy of a potentiometer is limited by the non-uniformity of the slid-wire, the uncertainty of the balance point, and the error in measuring the length
*l*of wire from the balance point to the end A. with even crude apparatus, the balance point can be located to within about 0.5 mm; if the length*l*is 50cm, or 500mm, then the error in locating the balance point is 1:1000. If the wire has been carefully treated, its non-uniformity may introduce an error of about same magnitude. The overall error is then about ten times less than that of a pointer instrument. A refined potentiometer has a still smaller error.

- The precision with which the balance-point of a potentiometer can be found depends on the sensitivity of the galvanometer the smallness of the current which will give a just-discernible deflection. A moving coil galvanometer must be protected by a series resistance R of several thousand ohms, which is shorted out when the balance is nearly reached. A series resistance is preferable to a shunt, because it reduces the current drawn from the cell under test, when the potentiometer is unbalanced. The process of seeking the balance-point then causes less change in the chemical condition of the cell, and therefore in its e.m.f

- It is important to realize that the accuracy of a potentiometer does not depend on the accuracy of the galvanometer, but only on its sensitivity. The galvanometer is used not to measure a current but merely to show one when the potentiometer is off balance. It is said to be used as a null-indicator, and the potentiometer method of measurement, like the bridge methods which we shall describe shortly, is called a null method.

- The current through the potentiometer wire must be steady it must not change appreciably between the finding of one balance-point and the next. The accumulator which provides it should therefore be neither freshly charged nor nearly run-down; when an accumulator is in either of those conditions its e.m.f. falls with time. Errors in potentiometer measurements may be caused by non-uniformity of the wire, and by the resistance of its connexion to the terminal at A. this resistance is added to the resistance of the length
*l*of the wire between A and the balance-point, and if it is appreciable it makes equation (11) invalid. Both these sources of error are eliminated in the Rayleigh potentiometer, which we shall describe later.

**Uses of the Potentiometer, E.M.F. and Internal Resistance**

All the use of the potentiometer depend on the fact that it can measure potential difference accurately, and without drawing current from the circuit under test.

If one of the cells in the diagram above has a known e.m.f., say E_{} then the e.m.f. of the other, E,is given by equation:

A cell of known e.m.f. is called a standard cell. The e.m.f.s of standard cells are determined absolutely that is to say, without reference to the emf.s of any other cell by methods which depend, in principle, on the definition of e.m.f. Standard cells are described along with the precautions which must be taken in their use. For simple experiments a Daniell cell, whose e.m.f. is about 1.1 volt, may be used as a standard.

The equation above is true only if the current I through the potentiometer wire has remained constant. The easiest way to check that it has done so is to balance the standard cell against the wire before and after balancing the unknown cell. If the lengths to the balance-point are equal within the limits of experimental error then the current I may be taken as constant. A check of this kind should be made in each of the experiments to be described.

The internal resistance of a cell, r, can be found with potentiometer by balancing first its e.m.f., E, and the its terminal potential difference, V, when a know resistance R is connected across it. Ohm’s law for the complete circuit gives

Where l and l’ are the lengths of potentiometer wire required to balance E and V. from equations (13) and (14), r can be found from

** **

**How to Caliberate a Voltmeter Using a Potentiometer**

The diagram below shows how a potentiometer can be used to calibrate a voltmeter. A standard cell is first used to find the p.d. per cm or volts per cm of wire: if its e.m.f. E_{} is balanced by a length l_{} then

Different voltages V_{m} are now applied to the voltmeter by the adjustable potential divider P. the fixed potential divider, comprising R_{1}R_{2}, gives a known fraction V of each value of V_{m} which is then balanced on the potentiometer:

(The resistance R_{1} and R_{2} are high of the order of 1000 to 10000 ohms, so that the voltage adjustment by P is fairly uniform. Their ratio is chosen so that the greatest value of V is measurable on the potentiometer about 1.5 volts.) if l is the lengths of potentiometer wire which balances a given value of V, then

V l x (volt/cm of wire)

From each value of V, the value of Vm is calculated by equation (16). If the voltmeter reading is Vobs; then the correction to be added to it is Vm – Vobs. This plotted against Vobs, as in the diagram below

** **

**How to Measure of Current On a Potentiometer**

A current can be measured on a potentiometer by means of the potential difference which it sets up across a known resistance, R in the first diagram below. The resistance is low, being chosen so that the potential difference across it is of the order of 0.1 volt. (A higher value is not chosen, because the voltage drop across the resistor disturbs the circuit in which it is inserted.) The second diagram below shows in detail the kind of resistor used, which is often called a standard shunt. It consists of a broad strip of alloy, such as manganin, whose resistance varies very little with temperature. The current is led in and out as the terminals I, i. the terminals v, v are connected to fine wires soldered to points PP on the strip; they are called the potential terminals. The marked value R of the resistance is the value between the points PP; it is adjusted by making hack –saw cuts into the edges of the strip.

As shown in the above diagram, the current to be measured, I_{1}, is passed through the shunt, and potential difference between its potential terminals, _{V}, is balanced on the potentiometer wire. If l is the length of wire to the balance point, then

Where E0 and l0 refer to a standard cell as before. The Equation above enables the current to be found in terms of *E _{o}, l_{o}, l,* and

*R*, since

V = *I _{1}R.*

The resistance of the wires connecting the potential terminals to the points PP, and to the potentiometer circuit, do not affect the result, because at the balance point the current through them is zero.

This method of measuring a current can be used to calibrate an ammeter, A and the results are treated in the same way as in the calibration of a voltmeter.

** How to Use a Potentiometer to Compare Resistances**

A potentiometer can be used to compare resistances, by comparing the potential differences across them when they are carrying the same current I_{1}. This method is particularly useful for very low resistances, because, as we have just seen, the resistances of the connecting wires do not affect the result of the experiment. It can, however, be used for higher resistances I desired. With low resistances the ammeter A’ and rheostat P are necessary to adjust the current to a value which will neither exhaust the accumulator Y, nor overheat the resistors. No standard cell is required. The potential difference across the first resistor, V_{1} = R_{1}l_{1}, is balanced against a length l_{1} of the potentiometer wire, as shown by the full lines in the figure. Both potential terminals

of R_{1} are then disconnected from the potentiometer, and those of R_{2} are connected in their place. If l_{2} is the length to the new balance point, then

This result is true only if the current I_{1} is constant; as well as the potentiometer current. The accumulator Y, as well as X, must therefore be in good condition. To check the constancy of the current I_{1}, the ammeter A’ is not accurate enough. The reliability of the experiment as a whole can be checked by balancing the potential V_{1} a second time, after V_{2}. If the new value of l_{1} differs from the original, then at least one of the accumulators is running down and must be replaced.

** The Rayleigh Potentiometer**

The image below shows a potentiometer devised by Lord Rayleigh (1842 – 1919), which is free from errors due to non-uniformity of the wire and to contact resistances at the end A. it consist of two plug-type resistance boxes, R_{1}, R_{2}, joined in series. (these boxes may well be the R-sections of two similar Post Office boxes). At the start of a measurement all the plugs of R_{1} are inserted, and all of R_{2} taken out. Then R_{1} is zero, and the main current *I* sets up on potential difference across it; but when the key K is pressed, the unknown e.m.f. E deflects the galvanometer. R_{1} is now increased by, say, 100 ohms, and R_{2} is decreased by the same amount. In this way R_{1} + R_{2} is kept constant, and the current I does not change. But there is now a potential difference across R_{1}, which opposes E. plugs are taken out of R_{1} and put into R_{2}, so as to keep R_{1} + R_{2} constant, until the galvanometer shows no deflection when K is pressed. If R’_{1} is the value of R_{1} at this point, then

The procedure is now repeated with a standard cell of e.m.f. E_{}, in place of R. sine R_{1} + R_{2} has been kept constant, the current* I* is the same as before; hence, if R”_{1} is the new value of R_{1} at balance,